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photothermocatalytic光热催化反应系统

PLR-GPTR Gas-solid photothermal reactor

PLR-GPTR系列气固相光热反应器

Column:光热催化反应系统Brand:PerfectlightViews:850
PLR-GPTR Gas-solid photothermal reactor
  • Introduction
  • Application
  • Literature
  • Maintenance

The PLR-GPTR Series Gas-Solid Photothermal Reactors consists of two products:

PLR-GPTR Gas-Solid Photothermal Reactor

PLR-GPTRT Gas-Solid Photothermal Reactor (Built-in Heating Version).

The PLR-GPTR Gas-Solid Photothermal Reactor comes in various models such as PLR-GPTR50T, PLR-GPTR100, PLR-GPTR200T, etc. The numerical suffix represents the effective volume of the reactor. For instance, "50" signifies a reactor with a volume of 50 mL, and "T" indicates a reactor with built-in heating functionality.

 

The PLR-GPTR Series Gas-Solid Photothermal Reactors are specifically designed for photothermal catalytic reactions. They employ a flask-type reactor, which is designed to be flat for gas-solid experiments. These reactors are equipped with pressure sensors to monitor pressure and temperature sensors for real-time monitoring of the catalyst's bulk-phase temperature.

In photothermal catalytic reactions, it is necessary to verify whether the reaction process is photothermal catalytic or photothermal-coupled catalytic. Comparative experiments are required to assess the conversion rate and selectivity at the corresponding temperature under photoreaction conditions compared to the same temperature under dark reaction conditions. This allows the determination of the impact of illumination on the reaction system and the extent of this impact during photothermal reactions.

To meet the demands of comparative experiments, the PLR-GPTRT Gas-Solid Photothermal Reactor (Built-in Heating Version) employs temperature feedback control design, providing localized heating only to the catalyst region. It can reach a maximum operating temperature of 300°C and offers 10-stage programmable temperature control with a control precision of ±0.5°C.

Key Features

● Thermocouple temperature measurement inside the reactor, displaying the bulk-phase temperature of the catalyst in real-time;
● High-pressure metal quick-connectors compatible with both batch and continuous flow reaction systems;
● Maximum operating temperature of 300°C with 10-stage programmable temperature control;
● Compact design, easy operation, standard Ф6 mm gas line fittings compatible with various detection equipment;
● Flat placement of powder catalysts for more efficient gas-catalyst contact;
● Customizable with different volumes and integrated water bath temperature control and various reactor structures.

Application Fields

▲ Gas-Solid Photothermal (Thermo)catalytic Reactions (e.g., CO₂ reduction, hydrogenation reactions, VOC degradation, nitrogen fixation, sulfur fixation, etc.)

Technical Specifications

PLR-GPTR Series Gas-Solid Photothermal Reactor Product Configuration Table
Model Volume/mL Built-in Heating Model Volume/mL Built-in Heating
PLR-GPTR 25 25 × PLR-GPTR 25 T 25
PLR-GPTR 50 50 PLR-GPTR 50 T 50
PLR-GPTR 100 100 PLR-GPTR 100 T 100
PLR-GPTR 200 200 PLR-GPTR 200 T 200

* All the above products can withstand a pressure of up to 0.3 MPa;

** None of the above products are equipped with a water jacket; please specify if needed.

 

Representative Literature

PLR-GPTR Representative Literature

  • Gas-Solid Photothermal/(Thermo)catalytic Reactions
  • CO2 Reduction
  • Hydrogenation Reactions
  • VOCs Degradation
  • Nitrogen Fixation
  • Sulfur Fixation
  • [1] Li Ruizhe, Ouyang Shuxin. A metal‐segregation approach to generate CoMn alloy for enhanced photothermal conversion of syngas to light olefins. Solar RRL 2020, 5:202000488. 
  • [2] G. Chen, L.Z. Wu, and Prof. T. Zhang , et. al. Alumina-Supported CoFe Alloy Catalysts Derived from Layered-Double-Hydroxide Nanosheets for Efficient Photothermal CO2 Hydrogenation to Hydrocarbons. Adv. Mater. 2018, 30, 1704663 
  • [3] Z. Li, L.Z. Wu and T. Zhang, et. al. Co-Based Catalysts Derived from Layered-Double-Hydroxide Nanosheets for the Photothermal Production of Light Olefins. Adv. Mater. 2018, 30, 1800527
  • [4] S. Q. Zhou, R. Shi and T. R. Zhang, et. al. Pd Single-Atom Catalysts on Nitrogen-Doped Graphene for the Highly Selective Photothermal Hydrogenation of Acetylene to Ethylene. Adv. Mater. 2019, 31, 1900509
  • [5] Xuyang Xiong,Chengliang Mao,Zhaojun Yang,Qinghua Zhang,Geoffrey I. N. Waterhouse,Lin Gu,Tierui Zhang,Photocatalytic CO2 Reduction to CO over Ni Single Atoms Supported on Defect-Rich Zirconia,Advanced Energy Materials,2020,2002928.
  • [6] Huining Huang, Run Shi, Zhenhua Li, Jiaqi Zhao, Chenliang Su, and Tierui Zhang,Triphase Photocatalytic CO2 Reduction over Silver-Decorated Titanium Oxide at a Gas-Water Boundary,Angew. Chem. Int. Ed. 2022, e202200802.
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